There's a lot going on here and my morning's a bit crazy here, so this may be a little disjointed...
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If I use CD input am I automatically in 2-channel mode, thus no center/dialog??
No. Each input (except for 7.1 Direct) has access to all of the 990's surround processing modes, and if the source is multichannel the 990 will preserve that. Additionally, the 990 will redirect center channel information from the center speaker to the fronts when there is no center speaker in the system.

I think you have missed a step in the 990's setup. Go back into the 990's setup menu and go to the menu called "SPEAKER SIZE." Fronts and surrounds should be "Small", center and surround back should be "None", and sub should be "Yes". Also, have you done any calibration (either the auto setup or a manual with SPL meter and the internal test tones)?

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Tried playing a music CD to check sound quality. Even though I set surround mode to either stereo or upsample, I had music from fronts and surround. I didn't think I would have the surrounds playing. Also, wasn't blown away by the sound. Movie sound tracks sound great, and I was really hoping the 2-channel sound would be even better.
You may have been using 5 Stereo, or there may be some other issue going on. Stereo and Upsample modes with a standard CD would only be two-channel, no surrounds engaged.

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I have the 990 set to small fronts with x-over set at 40, and LFE only to the sub. Sound is better, but I still feel like some thing is missing.
First, I'd bump the crossover up to 60Hz, but that's just fine-tuning. Also check to make sure the fronts are small, as it should not be possible to select "LFE Only" for the sub if the fronts are small.

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Any guidance for setting the BD player options for the best sound?
I'd have to get the manual for the player to answer that, especially since I've not used any Samsung players. Which Samsung do you have?
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Any guesses about the hum via the analog channels.
Sounds like a ground loop or similar interference. I'd start by checking to see how the analog cables are being routed - if they are parallel to a power cord, they are likely picking up some 60Hz noise from the power line.
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gonk
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