The performance of your system is not going to get much better by kicking the Pioneer out the door and replacing it with separates. The extra wattage available isn't enough to justify the expenditure. With two powered subs and efficient speakers the AVR isn't working very hard at all to provide the power to drive your 7.1 speakers. Remember that the heavy lifting of the low frequency stuff is being done by the subs amps which leaves the Pioneer lots of headroom to drive the other speakers to insane levels. You would be better served buying the Radioshack Sound meter and adjusting your room than going to separates, IMHO.
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Music system
Model 990/7500/Magnepan 1.6 QRs/Technics SL1200 MK2/Aperion S-12 Subwoofer/OWA3/Sony NS75H DVD
APC H15 Power Conditioner

TV System
Large Advent Loudspeakers/ Polk center/Monoprice surrounds/Panasonic Viera 42 inch/Onkyo HT-RC260/Sony BDP S590/Directv


Home Theater System
Onkyo PR-SC886/Outlaw 7125 Klipsch RF-82 L/R,RC-62 center, RB-35 SR/SL, BENQ HT1075, Outlaw LFM1-EX/OPPO BDP-83/Directv
Harmony ONE
Blue Jeans and Monoprice interconnects
APC H15 Power Conditioner