WW,
You could certainly try biamping, but in my experience, I've never noticed what I would call a significant improvement in sq by doing so. I'm sure there are others here that will have the opposite opinion. I guess you won't know til you try and see what you experience. If you don't you may always wonder what you've been missing and want to upgrade!
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HT:
Pioneer VSX-1120
Salk Songbirds, SongCenter, SongSurrounds
Panasonic BDP-45
Outlaw LFM-2

2 Channel:
Red Dragon M-500 monoblocks
BAT-VK3i
Salk HT-1TL's
Apple TV
Beresford 7520 DAC
Surgex XS10